• 文献标题:   Graphene-Based Hybrid Electrode Material for High-Power Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   KIM H, KIM SW, HONG J, LIM HD, KIM HS, YOO JK, KANG K
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF THE ELECTROCHEMICAL SOCIETY
  • ISSN:   0013-4651 EI 1945-7111
  • 通讯作者地址:   Seoul Natl Univ
  • 被引频次:   41
  • DOI:   10.1149/1.3599632
  • 出版年:   2011

▎ 摘  要

Graphene based hybrid electrode material is fabricated from an easy and simple chemical method and is demonstrated as a cathode material for Li rechargeable batteries with high capacity and excellent rate capability. The hybrid material delivers a specific capacity of 156 mAh g(-1) at a current rate of 25 mA g(-1) (0.125 C) after 100 cycles with coulombic efficiency of nearly 100%. At elevated current rates, the specific capacity of the hybrid material is over 100 mAh g(-1) even at a current rate of 2500 mA g(-1) (similar to 12.5 C). The excellent battery performance of the hybrid material is attributed to the easy Li ion and electron transport in the amorphous FePO4/graphene hybrid structure, in which electrochemically active amorphous FePO4 films are directly grown on graphene with superior electronic conductivity. (C) 2011 The Electrochemical Society. [DOI: 10.1149/1.3599632] All rights reserved.