• 文献标题:   Graphene Ionogel Ultra-Fast Filter Supercapacitor with 4 V Workable Window and 150 degrees C Operable Temperature
  • 文献类型:   Article
  • 作  者:   CHI FY, HU YJ, HE WY, WENG CX, CHENG HH, LI C, QU LT
  • 作者关键词:   alternating current ac linefiltering, graphene, high temperature environment, ionogel, ultrafast supercapacitor
  • 出版物名称:   SMALL
  • ISSN:   1613-6810 EI 1613-6829
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1002/smll.202200916 EA MAR 2022
  • 出版年:   2022

▎ 摘  要

The filtering capacitor plays an essential role in the ever-increasing electronics for current stability in complicated environments. However, because of the low specific capacitance and bulky volume, current filtering devices have difficulty satisfying the harsh temperature environment and small size for supercomputers, electric vehicles, aircraft and so on. Therefore, an ultra-fast electrochemical capacitor is developed on the basis of vertically oriented graphene iongel electrodes (GI-EC), which demonstrates excellent alternate current line-filtering performance with both hot tolerance of up to 150 degrees C and a wide voltage window of 4 V. Because of the particularly oriented graphene nanosheets induced fast ion transport, this ionic electrochemical capacitor displays a high areal specific energy density of 1784 mu F V-2 cm(-2) with a phase angle of -80.0 degrees (120 Hz) at 150 degrees C, which is greater than most of the reported electrochemical capacitors. Moreover, it can filter arbitrary waveforms to smooth direct current signals and works well with a wide frequency range from 10 to 10(4) Hz. The easy integration of GI-ECs in series or parallel can also further deliver desired capacitances or high voltages. The GI-EC with high-rate performance, wide voltage window, and high-temperature adaptability presents a great promise for universally applicable filtering capacitors.