• 文献标题:   Tight-binding approximation for bulk and edge electronic states in graphene
  • 文献类型:   Article
  • 作  者:   DOBRESCU OA, APOSTOL M
  • 作者关键词:  
  • 出版物名称:   CANADIAN JOURNAL OF PHYSICS
  • ISSN:   0008-4204 EI 1208-6045
  • 通讯作者地址:   Inst Atom Phys
  • 被引频次:   2
  • DOI:   10.1139/cjp-2014-0313
  • 出版年:   2015

▎ 摘  要

The tight-binding approximation is employed here to investigate electronic bulk and edge ("surface") states in semi-infinite graphene sheets and graphene monolayer ribbons with various edge terminations (zigzag, horseshoe, and armchair edges). It is shown that edge states do not exist for a uniform hopping (transfer) matrix. The problem is generalized to include edge elements of the hopping matrix distinct from the infinite-sheet ("bulk") ones. In this case, semi-infinite graphene sheets with zigzag or horseshoe edges exhibit edge states, while semi-infinite graphene sheets with armchair edges do not. The energy of the edge states lies above the (zero) Fermi level. Similarly, symmetric graphene ribbons with zigzag or horseshoe edges exhibit edge states, while ribbons with asymmetric edges (zigzag and horseshoe) do not. It is also shown how to construct the "reflected" solutions (bulk states) for the intervening equations with finite differences both for semi-infinite sheets and ribbons.