• 文献标题:   Layer-by-layer self-assembly of graphene-like Co3O4 nanosheet/graphene hybrids: Towards high-performance anode materials for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   YANG Q, WU J, HUANG K, LEI M, WANG WJ, TANG SS, LU PJ, LU YK, LIU J
  • 作者关键词:   graphene, ultrathin colbaltosic oxide nanosheet, anode, sandwichlike nanostructure
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   16
  • DOI:   10.1016/j.jallcom.2016.01.136
  • 出版年:   2016

▎ 摘  要

We have successfully synthesized graphene-like Co(OH)(2) and fabricated sandwich-like Co(OH)(2)/graphene hybrids by the electrostatic self-assembly. After annealing at low temperatures, we further fabricated Co3O4 nanosheet/graphene hybrids, in which the thickness of graphene-like Co3O4 nanosheets is only similar to 5 nm. The as-prepared product exhibits a very high reversible lithium storage capacity up to 982.6 mAh g(-1) after 50 cycles, while pure Co3O4 nanosheets only show the discharge capacity of 108 mAh g(-1) after 50 cycles. Moreover, in comparison with the reported results, it exhibits an ultrahigh rate capability of 209.7 mAh g(-1) at 5000 mA g(-1). The greatly improved electrochemical performances may be ascribed to the sandwich-like structure of ultrathin Co3O4 nanosheet/graphene. (c) 2016 Elsevier B.V. All rights reserved.