• 文献标题:   The improved electrocatalytic activity of palladium/graphene nanosheets towards ethanol oxidation by tin oxide
  • 文献类型:   Article
  • 作  者:   WEN ZL, YANG SD, LIANG YY, HE W, TONG H, HAO LA, ZHANG XG, SONG QJ
  • 作者关键词:   sno2gns, catalyst support, microwaveassisted reduction, electrocatalytic performance, ethanol oxidation
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Nanjing Univ Aeronaut Astronaut
  • 被引频次:   65
  • DOI:   10.1016/j.electacta.2010.09.032
  • 出版年:   2010

▎ 摘  要

Tin oxide (SnO2)/graphene nanosheets (GNS) composite was prepared by a simple chemical-solution method as the catalyst support for direct ethanol fuel cells. Then the SnO2-GNS composites supporting Pd (Pd/SnO2-GNS) catalysts were synthesized by a microwave-assisted reduction process. The Pd/SnO2-GNS catalysts were characterized by using X-ray diffraction, transmission electron microscopy and energy-dispersive spectroscopy techniques. The electrocatalytic performances of Pd/SnO2-GNS catalysts for ethanol oxidation were studied by cyclic voltammetric and chronoamperometric measurements. It was found that compared with Pd/GNS, the Pd/SnO2-GNS catalyst showed superior electrocatalytic activity for ethanol oxidation when the mass ratio of SnCl2 center dot 2H(2)O precursor salt to graphite oxide was about 1:2. (C) 2010 Elsevier Ltd. All rights reserved.