• 文献标题:   Comparison of catalytic performance of different types of graphene in Li-O-2 batteries
  • 文献类型:   Article
  • 作  者:   PARK JE, LEE GH, CHOI M, DAR MA, SHIM HW, KIM DW
  • 作者关键词:   lio2 batterie, graphene, pore volume, catalytic performance, electrochemical performance
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Korea Univ
  • 被引频次:   9
  • DOI:   10.1016/j.jallcom.2015.05.200
  • 出版年:   2015

▎ 摘  要

We report comparative catalytic studies of two types of commercial graphene nanoplatelets as electrode materials with different physical properties for Li-O-2 batteries. The graphene nanoplatelets were characterized by field-emission scanning electron microscopy, transmission electron microscopy, N-2 physisorption, X-ray photoelectron spectroscopy, and Raman spectroscopy. The electrochemical performance of the graphene nanoplatelets, which have large pore volume density, large pore diameter, and high population of defect sites, was evaluated using galvanostatic dischargeecharge cycling and a depthof- discharge test. Higher specific capacity of the Li-O-2 battery was achieved when graphene nanoplatelets were used as an electrode material; this specific capacity could be associated with pore volume density, pore diameter, and number of defects in the graphene nanoplatelets. (C) 2015 Elsevier B.V. All rights reserved.