• 文献标题:   In- situ carbon-coated Na2FeP2O7 anchored in three-dimensional reduced graphene oxide framework as a durable and high-rate sodium-ion battery cathode
  • 文献类型:   Article
  • 作  者:   CHEN XB, DU K, LAI YQ, SHANG GZ, LI HX, XIAO ZW, CHEN YX, LI JM, ZHANG ZA
  • 作者关键词:   graphene oxide, cathode, iron pyrophosphate, sodium ion batterie
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   14
  • DOI:   10.1016/j.jpowsour.2017.04.075
  • 出版年:   2017

▎ 摘  要

Na2FeP2O7, which is considered as a promising cathode for sodium ion batteries (SIBs) on account of its economical efficiency and outstanding thermal stability, has been widely studied for the purpose of enhancing its electronic conductivity and interface ion transportation. In this paper, a double-carbon synergistically modified strategy was firstly introduced to facilitate the electrochemical performance of Na2FeP2O7. Na2FeP2O7 particles are enwrapped in situ by a carbon layer and further anchored in reduced graphene oxide (RGO) framework through a facile urea-nitrate combustion method. Consequently, the excellent rate performance and durable cycle stability of this compound are identified, which exhibits a reversible sodium storage capacity of 65 mAh g(-1) at a current density of 10 C and no obvious decay in capacity after circling for 300 cycles at 1 C. What's more, no drastic degradation in capacity is observed when the cycling current density is brought back to high rates after cycling for more than 360 cycles at various rates. (C) 2017 Elsevier B.V. All rights reserved.