• 文献标题:   Conducting Polymer Coated Graphene Oxide Electrode for Rechargeable Lithium-Sulfur Batteries
  • 文献类型:   Article
  • 作  者:   LEE HY, JUNG Y, KIM S
  • 作者关键词:   reduced graphene oxide, sulfur, conducting polymer, lithiumsulfur battery
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Pusan Natl Univ
  • 被引频次:   11
  • DOI:   10.1166/jnn.2016.11061
  • 出版年:   2016

▎ 摘  要

Poly(diallyldimethylammonium chloride) (PDDA)/graphene oxide-sulfur composites were prepared by a chemical oxidation method. For the PDDA-GO composites, conducting polymers (PDDA) were coated on the surface of GO sheets. PDDA-GO composites could be expected to increase electrical conductivity and protect restacking of graphene sheets. And then, sulfur particles were dispersed into the PDDA-GO composites by mixing in the CS2 solvent. It is expected the PDDA-GO/S composites show the limited release of polysulfides due to the fact that it can provide high surface area, because conducting polymer can be used as spacer between graphene sheets. Electrochemical performances of prepared composites were characterized by cyclic voltammetry (CV). The PDDAGO/ S composites showed a high discharge capacity of 1102 mAh g(-1) at the first cycle and a good cycle retention of 60% after 100 cycles.