• 文献标题:   Microstructural analysis and thermoelectric performance of Ga-doped ZnO/reduced graphene oxide thin film nanocomposites
  • 文献类型:   Article
  • 作  者:   TRINH TQ, NGUYEN TT, VU DV, LE DH
  • 作者关键词:   gadoped zno, rgo, nanocomposite film, power factor, thermoelectric
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1016/j.ceramint.2021.08.092 EA SEP 2021
  • 出版年:   2021

▎ 摘  要

In this work, n-type Ga-doped ZnO (GZO)/reduced graphene oxide (rGO) thin-film nanocomposites were investigated as an approach to enhancing the electron transport of a popular material having weak thermoelectric properties. Namely, the rGO contents of 1, 3, 5, and 7 wt% were mixed in the matrix of chemically derived GZO. The XRD, Raman, XPS spectroscopies, and SEM mapping indicated and confirmed the presence of rGO in the thin-film nanocomposites having good density, nanoscale grains, and stoichiometry of elements in the composition. In this case, rGO sheets enclosed in the grain boundaries of polycrystalline GZO behaved as bridge, which facilitated electron transport and effectively improved the thermoelectric performance of the film nanocomposites. Consequently, the magnitude of the electrical conductivity and power factor of the samples increased by four to five times larger than those of rGO-free GZO ones in the range from room temperature to 400 degrees C. The obtained results provide promising perspectives of a binary composite material made of environmentally benign, earth-abundant elements, and fabricated by a simple and low-cost process for thermoelectric applications.