• 文献标题:   Development of a Potentiometric Chemical Sensor for the Rapid Detection of Carbofuran Based on Air Stable Lipid Films with Incorporated Calix[4]arene Phosphoryl Receptor Using Graphene Electrodes
  • 文献类型:   Article
  • 作  者:   BRATAKOU S, NIKOLELI GP, NIKOLELIS DP, PSAROUDAKIS N
  • 作者关键词:   stabilized lipid film, carbofuran chemical sensor, calix4arene phosphoryl receptor, potentiometric chemical sensor, graphene nanosheet
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Univ Athens
  • 被引频次:   9
  • DOI:   10.1002/elan.201500299
  • 出版年:   2015

▎ 摘  要

The present article describes a miniaturized potentiometric carbofuran chemical sensor on graphene nanosheets with incorporated lipid films. The graphene electrode was used for the development of a very selective and sensitive chemical sensor for the detection of carbofuran by immobilizing an artificial selective receptor on stabilized lipid films. The artificial receptor was synthesized by transformation of the hydroxyl groups of resorcin[4]arene receptor into phosphoryl groups. This chemical sensor responded for the wide range of carbofuran concentrations with fast response time of ca. 20 s. The presented potentiometric carbofuran chemical sensor is easy to construct and exhibits good reproducibility, reusability, selectivity, rapid response times, long shelf life and high sensitivity of ca. 59 mV/decade over the carbofuran logarithmic concentration range from 10(-6) to 10(-3) M.