• 文献标题:   Thermally reduced graphene oxide acting as a trap for multiwall carbon nanotubes in bi-filler epoxy composites
  • 文献类型:   Article
  • 作  者:   CHANDRASEKARAN S, FAIELLA G, PRADO LASA, TOLLE F, MULHAUPT R, SCHULTE K
  • 作者关键词:   polymer matrix composites pmcs, rheological propertie, electrical propertie
  • 出版物名称:   COMPOSITES PART AAPPLIED SCIENCE MANUFACTURING
  • ISSN:   1359-835X
  • 通讯作者地址:   Tech Univ Hamburg
  • 被引频次:   27
  • DOI:   10.1016/j.compositesa.2013.02.008
  • 出版年:   2013

▎ 摘  要

The effect of thermally reduced graphene oxide (TRGO) on the electrical percolation threshold of multi wall carbon nanotube (MWCNT)/epoxy cured composites is studied along with their combined rheological/electrical behavior in their suspension state. In contrast to MWCNT and carbon black (CB) based epoxy composites, there is no prominent percolation threshold for the bi-filler (TRGO-MWCNT/epoxy) composite. Furthermore, the electrical conductivity of the bi-filler composite is two orders of magnitude lower (similar to 1 x 10(-5) S/m) than the pristine MWCNT/epoxy composites (similar to 1 x 10(-3) S/m). This result is primarily due to the strong interaction between TRGO and MWCNTs. Optical micrographs of the suspension and scanning electron micrographs of the cured composites indicate trapping of MWCNTs onto TRGO sheets. A morphological model describing this interaction is presented. (C) 2013 Elsevier Ltd. All rights reserved.