• 文献标题:   High Voltage Li-Ion Battery Using Exfoliated Graphite/Graphene Nanosheets Anode
  • 文献类型:   Article
  • 作  者:   AGOSTINI M, BRUTTI S, HASSOUN J
  • 作者关键词:   graphene, graphite, anode, highvoltage, lithiumion battery
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Univ Ferrara
  • 被引频次:   29
  • DOI:   10.1021/acsami.6b01407
  • 出版年:   2016

▎ 摘  要

The achievement of a new generation of lithium-ion battery, suitable for a continuously growing consumer electronic and sustainable electric vehicle markets, requires the development of new, low-cost, and highly performing materials. Herein, we propose a new and efficient lithium ion battery obtained by coupling exfoliated graphite/graphene nanosheets (EGNs) anode and high-voltage, spinel-structure cathode. The anode shows a capacity exceeding by 40% that ascribed to commercial graphite in lithium half-cell, at very high C-rate, due to its particular structure and morphology as demonstrated by X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The Li-ion battery reveals excellent efficiency and cycle life, extending up to 150 cycles, as well as an estimated practical energy density of about 260 Wh kg(-1), that is, a value well exceeding the one associated with the present-state Li-ion battery.