• 文献标题:   One-pot sonochemical synthesis of magnetite@reduced graphene oxide nanocomposite for high performance Li ion storage
  • 文献类型:   Article
  • 作  者:   WU KP, LIU DW, LU WW, ZHANG KB
  • 作者关键词:   sonochemical synthesi, fe3o4@rgo, nanocomposite, electrochemical performance
  • 出版物名称:   ULTRASONICS SONOCHEMISTRY
  • ISSN:   1350-4177 EI 1873-2828
  • 通讯作者地址:   Southwest Univ Sci Technol
  • 被引频次:   1
  • DOI:   10.1016/j.ultsonch.2018.03.015
  • 出版年:   2018

▎ 摘  要

In this research, we introduce a one-pot sonochemical method for the fabrication of magnetite@reduced graphene oxide (Fe3O4@rGO) nanocomposite as anode material for Li-ion batteries. Fe3O4@rGO is synthesized under ultrasonic is-radiations by using iron (II) salt and GO as raw materials. An in-situ oxidation-reduction occurs between GO and Fe2+ during the ultrasonic chemical reaction process. Fe3O4 particles with the size of similar to 20 nm are uniformly deposited on the surface of rGO nanosheets. The electrochemical activity of Fe3O4@rGO is systematically evaluated as an anode material in Li-ion battery. Li-ion cells using Fe3O4@rGO as electrode deliver high discharge and charge capacities of 1433.6 and 907.8 mAh g(-1) in the initial cycle at 200 mA g(-1) Even performed at 500 and 5000 mA g(-1), it is able to deliver reversible capacities of 846.4 and 355.6 mAh g(-1), respectively, demonstrating outstanding Li-ion storage performance. This research presents a straightforward and efficient method for the fabrication of Fe3O4@rGO, which holds great potential in synthesis of other metal oxides on graphene sheets.