• 文献标题:   Graphene oxide-integrated high-temperature durable fluoroelastomer for petroleum oil sealing
  • 文献类型:   Article
  • 作  者:   WEI JH, JACOB S, QIU JJ
  • 作者关键词:   particlereinforce composite, curing, mechanical propertie, nano composite, solgel method
  • 出版物名称:   COMPOSITES SCIENCE TECHNOLOGY
  • ISSN:   0266-3538 EI 1879-1050
  • 通讯作者地址:   Texas Tech Univ
  • 被引频次:   30
  • DOI:   10.1016/j.compscitech.2013.12.010
  • 出版年:   2014

▎ 摘  要

Two-dimensional one-atom thick graphene inspires intensive studies due to its great potentials in enhancing polymer's mechanical, gas/liquid barrier, and thermal properties. However, its poor dispersion within highly viscous rubber elastomers by conventional mill mixing posed significant technical challenges and hindered its vast applications. In this paper, graphene oxide (GO) enhanced fluoroelastomer (FKM) was solution-processed to enhance the mechanical and liquid barrier properties of FKM for the first time. Due to the chemical bonding, the GO/FKM performed 1.5-fold increment tensile strength compared with pure FKM and 1.2-fold increment tensile strength compared with Reduced Graphene Oxide/FKM at 150 degrees C. The reduced permeability of GO/FKM to organic solvent (such as methyl ethyl ketone) indicated the improved liquid barrier properties. This research provides a cost-effective solution process to efficiently enhance the thermal mechanical and liquid barrier properties of FKM with the addition of GO sheets through excellent dispersion techniques and strong GO-matrix bonding. (C) 2013 Elsevier Ltd. All rights reserved.