• 文献标题:   Accelerated hydrothermal aging of cycloaliphatic epoxy/graphene nanoparticle composites
  • 文献类型:   Article
  • 作  者:   TOMASI JM, HELMAN ID, PISANI WA, KLIMEKMCDONALD DR, CHINKANJANAROT S, MISKIOGLU I, KING JA, ODEGARD GM
  • 作者关键词:   nanocomposite, degradation, hygrothermal, weathering
  • 出版物名称:   POLYMER DEGRADATION STABILITY
  • ISSN:   0141-3910 EI 1873-2321
  • 通讯作者地址:   Michigan Technol Univ
  • 被引频次:   5
  • DOI:   10.1016/j.polymdegradstab.2016.08.009
  • 出版年:   2016

▎ 摘  要

Cycloaliphatic epoxy (CE) resin systems are of primary interest in applications that require improved resistance to harsh conditions relative to other epoxy systems. Because other epoxy systems have demonstrated improved resistance to hydrothermal aging with the addition of carbon-based nano particle reinforcement, it is expected that the hydrothermal resistance of CE resins will likewise be improved with incorporation of nanoparticles. Therefore, the objective of this study is to determine the influence of graphene nanoparticles (GNP) on the hydrothermal aging resistance of CE resins. CE specimens are fabricated with varying levels of GNP and exposed to elevated temperatures and moisture levels for varying amounts of time up to 400 h. The results from flexure and dynamical-mechanical testing indicate that the addition of GNP provides modest improvements in the stiffness and glass transition temperature for all aging levels, while the strength is improved for aging times below 400 h. (C) 2016 Elsevier Ltd. All rights reserved.