• 文献标题:   Catalytic activity of Mn(III) porphyrins supported onto graphene oxide nano-sheets for green oxidation of sulfides
  • 文献类型:   Article
  • 作  者:   RAYATI S, REZAIE S, NEJABAT F
  • 作者关键词:   manganese porphyrin, graphene oxide, heterogenized catalyst, urea hydrogen peroxide, sulfide
  • 出版物名称:   JOURNAL OF COORDINATION CHEMISTRY
  • ISSN:   0095-8972 EI 1029-0389
  • 通讯作者地址:   KN Toosi Univ Technol
  • 被引频次:   4
  • DOI:   10.1080/00958972.2019.1610562 EA MAY 2019
  • 出版年:   2019

▎ 摘  要

In this research, oxidation of various sulfides with urea hydrogen peroxide (UHP) in the presence of manganese porphyrin grafted onto graphene oxide ([Mn(THPP)OAc@GO]) in ethanol was studied. The heterogenized catalyst was characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-transform infrared (FT-IR), and UV-Vis spectroscopy. The amount of Mn-porphyrin loaded on the GO nano-sheets was determined by atomic absorption spectroscopy (AAS) and the thermal stability of the heterogenized catalyst was investigated by thermo-gravimetric analysis (TGA). [Mn(THPP)OAc@GO] was applied for the green oxidation of different sulfides and the solid catalyst can be simply reused several times without losing its catalytic efficiency.