• 文献标题:   MnCo2O4/graphene composites anchored on Ni foam as binder-free anode with enhanced lithium-storage performance
  • 文献类型:   Article
  • 作  者:   YAO LB, WU JJ, DENG HH, HUANG QA, SU QM, DU GH
  • 作者关键词:   nanocomposite, microstructure, electron microscopy, lithium storage
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Zhejiang Normal Univ
  • 被引频次:   9
  • DOI:   10.1016/j.matlet.2016.05.177
  • 出版年:   2016

▎ 摘  要

We present a novel strategy to prepare MnCo2O4/graphene composites on nickel foam. TEM analysis reveals that high density of MnCo2O4 nanoparticles of similar to 5-10 nm are uniformly anchored on graphene nanosheets. The MnCo2O4/graphene-anchored Ni foams are used as binder -free integrated anodes for lithium ion batteries (LIBs) and exhibit superior lithium -storage performance. The MnCo2O4/graphene composites exhibit high cycling stability (868 mAh/g at 100 mA/g) and good rate capacity (607 mAh/g at 1.6 A/g) as anode materials for LIBs. The prominent electrochemical performance is associated with the synergistic effects of 3D porous Ni foam and graphene, which promote electron transfer and buffer the large volume fluctuation of metal oxides during the lithiation/delithiation progress. (C) 2016 Elsevier B.V. All rights reserved.