• 文献标题:   Recyclable Pd-graphene catalyst: mechanistic insights into heterogeneous and homogeneous catalysis
  • 文献类型:   Article
  • 作  者:   NISHINA Y, MIYATA J, KAWAI R, GOTOH K
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Okayama Univ
  • 被引频次:   42
  • DOI:   10.1039/c2ra21185h
  • 出版年:   2012

▎ 摘  要

Pd-graphene, a composite of Pd nanoparticles and exfoliated graphene, was used as a catalyst in organic reactions. In the Suzuki-Miyaura cross-coupling reaction, Pd-graphene showed high reusability without aggregation of Pd nanoparticles. The intermediates of the reaction in the liquid phase, Ph-Pd-Br and Ph-Pd-OH, were detected by ESI-MS.