• 文献标题:   Graphene-Pt\ITO counter electrode to significantly reduce Pt loading and enhance charge transfer for high performance dye-sensitized solar cell
  • 文献类型:   Article
  • 作  者:   GUAI GH, SONG QL, GUO CX, LU ZS, CHEN T, NG CM, LI CM
  • 作者关键词:   graphene, platinum, counter electrode, charge transfer, dyesensitized solar cell
  • 出版物名称:   SOLAR ENERGY
  • ISSN:   0038-092X
  • 通讯作者地址:   Nanyang Technol Univ
  • 被引频次:   40
  • DOI:   10.1016/j.solener.2012.04.006
  • 出版年:   2012

▎ 摘  要

A graphene-Pt\ITO (ITO-PG) counter electrode is fabricated by electrochemical deposition of a porous graphene film on a low-loaded Pt\ITO electrode. Compared to both plain graphene and Pt films, the graphene-coated Pt composite film provides large and superior conductive interface for significant improvement of Pt utilization efficiency and charge transfer, which in turn leads to higher power conversion efficiency of the dye-sensitized solar cell (DSSC). As compared to conventional Pt-coated counter electrode, the Pt loading of ITO-PG electrode can be reduced by more than 60% to 1.9 mu g cm(-2) while achieving even better performance. The performance enhancement mechanism is proposed. This work renders an economical manufacturing process to fabricate high performance DSSC for potential commercial production. (C) 2012 Elsevier Ltd. All rights reserved.