• 文献标题:   Microwave-Assisted Synthesis and Physicochemical Characterization of Tetrafuranylporphyrin-Grafted Reduced-Graphene Oxide
  • 文献类型:   Article
  • 作  者:   BOSCA F, ORIO L, TAGLIAPIETRA S, CORAZZARI I, TURCI F, MARTINA K, PASTERO L, CRAVOTTO G, BARGE A
  • 作者关键词:   dielsalder reaction, graphene grafting, microwave, modified porphyrin, reduced graphene oxide
  • 出版物名称:   CHEMISTRYA EUROPEAN JOURNAL
  • ISSN:   0947-6539 EI 1521-3765
  • 通讯作者地址:   Univ Turin
  • 被引频次:   10
  • DOI:   10.1002/chem.201503887
  • 出版年:   2016

▎ 摘  要

This work describes the design of a modified porphyrin that bears four furan rings linked by 1,2-bis-(2-aminoethoxy) ethane spacers. This unit is a well-suited scaffold for a Diels-Alder reaction with commercial reduced-graphene oxide, which is also described in this paper. A new hybrid material is obtained, thanks to efficient grafting under microwave irradiation, and fully characterized in terms of structure (UV, TGA, Raman) and morphology (HR-TEM and AFM). Potential applications in photo-and sonodynamic therapy are envisaged.