• 文献标题:   Determination of Pb(II) and Cd(II) by Graphite Furnace Atomic Absorption Spectrometry after Preconcentration with Graphene-Titanium Dioxide Composites
  • 文献类型:   Article
  • 作  者:   GU XW, LU XJ, JIA Q, ZHOU WH, LIU YL
  • 作者关键词:   graphenetitanium dioxide composite, graphite furnace atomic absorption spectrometry, lead, cadmium
  • 出版物名称:   CHINESE JOURNAL OF ANALYTICAL CHEMISTRY
  • ISSN:   0253-3820
  • 通讯作者地址:   Jilin Univ
  • 被引频次:   3
  • DOI:   10.3724/SP.J.1096.2013.20748
  • 出版年:   2013

▎ 摘  要

A method for the determination of lead and cadmium was developed with graphene-TiO2 composites (GN-TiO2) as adsorbents combined with graphite furnace atomic absorption spectrometry. Effects of various experimental conditions on the adsorption capacity were investigated. The optimized conditions were: sample pH as 5.0, contact time as 60 min, and adsorbent dosage as 0.02 g. Results showed that the processes could be simulated by a pseudo-second-order model. The adsorption process was proved to be an endothermic one. LODs of lead and cadmium of the developed method were calculated as 0.086 mu g/L and 0.006 mu g/L with RSDs of 3.2% and 2.5%, respectively. Furthermore, the present method was applied to the determination of lead and cadmium in different reference materials and real tea samples with satisfactory results.