• 文献标题:   Synthesis, characterisation and corrosion inhibition assessment of a novel ionic liquid-graphene oxide nanohybrid
  • 文献类型:   Article
  • 作  者:   MOBIN M, HUDA, SHOEB M, ASLAM R, BANERJEE P
  • 作者关键词:   ionic liquid, graphene oxide nanohybrid, corrosion inhibitor, mild steel, adsorption
  • 出版物名称:   JOURNAL OF MOLECULAR STRUCTURE
  • ISSN:   0022-2860 EI 1872-8014
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1016/j.molstruc.2022.133027 EA APR 2022
  • 出版年:   2022

▎ 摘  要

A novel ionic liquid, L-proline nitrate and graphene oxide nanohybrid (IL-GO), was synthesized and characterised by FTIR, UV-Vis, H-1 NMR,C-13 NMR and HR-TEM. The corrosion inhibition potency of IL-GO nanohybrid for mild steel in M-1 HCl was examined by gravimetric measurements, electrochemical methods supplemented with SEM-EDS, XPS, contact angle measurement, and FTIR. The experimental results supported that IL-GO endowed fairly good corrosion inhibition response in the temperature range 303- 353 K. Inhibition efficiency raised with inhibitor concentration, reaching 86.5% at 250 ppm and falling above 333 K. Adsorption of IL-GO over mild steel surface suited well with Langmuir model involving both chemisorption and physisorption interactions. Electrochemical results demonstrated that IL-GO remarkably resisted charge transfer process across the mild steel-solution interface and functioned as mixed type inhibitor. SEM-EDS and XPS studies verified the adsorption of IL-GO nanohybrid and fabrication of a physical barrier film at the metal surface. (C) 2022 Elsevier B.V. All rights reserved.