• 文献标题:   Adsorption of pure SO2 on nanoscaled graphene oxide
  • 文献类型:   Article
  • 作  者:   BABU DJ, KUHL FG, YADAV S, MARKERT D, BRUNS M, HAMPE MJ, SCHNEIDER JJ
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Tech Univ Darmstadt
  • 被引频次:   20
  • DOI:   10.1039/c6ra07518e
  • 出版年:   2016

▎ 摘  要

Adsorption of pure SO2 is studied for the first time on graphene oxide (GO). The adsorption mechanism was found to be fundamentally different from conventional carbon materials like activated carbon or carbon fibers. Itwas observed that GObinds SO2 only by physisorption (Delta H-ads = 18.04 kJmol(-1)) and still the adsorption capacity was found to be comparable to traditional adsorbents like activated carbon or carbon molecular sieves. The 2D layered morphology as well as the absence of extensive micropores well known to promote SO2 to SO3 conversion are responsible for the observed physisorption characteristics.