▎ 摘　　要

Two dimensional (2D) nitrogen-doped graphene@amorphous carbon was constructed by in-situ polymerization of sandwich-like structured polyaniline/graphene oxide composites then carbonization at 650 degrees C in vacuum. The results revealed that the as-prepared 2D N-doped graphene@amorphous carbon and N-doped amorphous carbon nanorods have almost the same decomposition degree and crystal structure. However larger defective degree and more polar bonds are conducive to enhance the polarization loss capacity, and larger dielectric constant can contribute to prominent conductive loss potential. The standing-wave ratio at 13.325 GHz of 2D N-doped graphene@amorphous carbon is 1.08426 approaching to 1, almost perfect impedance-matching level achieving. HFSS simulations certify phase mutation, group delay and the resonance response between N-doped graphene@amorphous carbon and testing microwave, as well as the stronger microwave loss capacity and better impedance matching. Both of the above make 2D N-doped graphene@amorphous carbon a promising microwave absorbing material. The minimum reflection loss (RL) of nitrogen-doped graphene@amorphous carbon can reach -29.5 dB and the effective absorbing bandwidth (EAB, RL < -10 dB) can reach 5.355 GHz ranging from 12.56 to 17.915 GHz only at a thickness of 2.25 mm.