• 文献标题:   L-Cysteine-assisted hydrothermal synthesis of nickel disulfide/graphene composite with enhanced electrochemical performance for reversible lithium storage
  • 文献类型:   Article
  • 作  者:   CHEN QN, CHEN WX, YE JB, WANG Z, LEE JY
  • 作者关键词:   nis2/graphene composite, lcysteine, hydrothermal reaction, electrochemical lithium storage, lithium ion battery, anode material
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   34
  • DOI:   10.1016/j.jpowsour.2015.06.071
  • 出版年:   2015

▎ 摘  要

NiS2/graphene composite is synthesized by a facile hydrothermal reaction between NiCl2 and L-cysteine in the presence of graphene oxide sheets. L-Cysteine serves as both the sulfur source for NiS2 and reductant for reduction of graphene oxide sheets. The reduced graphene oxides can be used as a platform for growth of NiS2 particles and restrain NiS2 from agglomerating during hydrothermal process. The results of characterizations show that the sphere-like NiS2 particles exhibit smaller sizes and are well dispersed on the surface of reduced graphene sheets. The electrochemical measurements demonstrate that the NiS2/graphene composite delivers a reversible capacity as high as 1200 mAh g(-1) at a current density of 100 mA g(-1) and enhanced high-rate capability of 740 mAh g(-1) at a high current density of 1000 mA g(-1). After 1000 cycles, the NiS2/graphene still preserves the reversible capacity about 810 mAh g(-1) at a current density of 500 mA g(-1), indicating its excellent cyclic stability. (C) 2015 Elsevier B.V. All rights reserved.