• 文献标题:   Direct conversion of lignin to high-quality graphene-based materials via catalytic carbonization
  • 文献类型:   Article
  • 作  者:   ISHII T, MORI M, HISAYASU S, TAMURA R, IKUTA Y, FUJISHIRO F, OZAKI JI, ITABASHI H, MORI M
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1039/d1ra02491d
  • 出版年:   2021

▎ 摘  要

Methods for effectively utilizing lignin are necessary for the realization of a sustainable society. Herein, we report a method for directly converting lignin to graphene-based materials. Fe-supported lignin is prepared by dissolving lignin in an aqueous FeCl2 solution, followed by freeze drying. Graphene is then produced by catalytically carbonizing this Fe-supported lignin at 1200 degrees C. The characteristics of both the Fe catalyst and lignin are crucial for the production of high-quality graphene. Specifically, the lignin should disperse well in water, freeze dry, and carbonize via solid-state carbonization. The obtained graphene-based material is highly resistant to electrochemical oxidation, as observed in other graphene-based materials. The direct conversion of lignin to graphene described herein is an unprecedented method for synthesizing large amounts of graphene-based material at low cost, as well as being an excellent use for lignin.