• 文献标题:   Effect of Octadecylamine Modified Graphene on Thermal Stability, Mechanical Properties, and Gas Barrier Properties of Brominated Butyl Rubber
  • 文献类型:   Article
  • 作  者:   YANG XY, ZHANG Y, XU Y, GAO S, GUO S
  • 作者关键词:   graphene, brominated butyl rubber biir, thermal stability, mechanical propertie, gas barrier propertie
  • 出版物名称:   MACROMOLECULAR RESEARCH
  • ISSN:   1598-5032 EI 2092-7673
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   12
  • DOI:   10.1007/s13233-017-5035-7
  • 出版年:   2017

▎ 摘  要

Graphene oxide (GO) was modified with octadecylamine (ODA) in ethyl alcohol solution to obtain GOODA hybrid. GO-ODA/brominated butyl rubber (BIIR) composites were obtained by solution mixing, in which GO-ODA was well dispersed in nano-sized as confirmed by transmission electron microscope images. The GO-ODA/BIIR composites had much better mechanical properties than BIIR. The stress at 300% extension of BIIR increased 230% after the addition of 10 phr GO-ODA. The improved mechanical properties benefited from the strong interaction between GO-ODA and BIIR. The heat resistance of GO-ODA/BIIR composites was improved with increasing GO-ODA loading. GO-ODA/BIIR nanocomposites had better gas barrier properties than BIIR, and the gas transmission rate of GO-ODA/BIIR (10/100) nanocomposite was only 21.2% of that of BIIR. The improved mechanical, heat resistance and gas barrier properties bring BIIR the potential to be used in a wider range of application areas.