• 文献标题:   A catalytic alloy approach for graphene on epitaxial SiC on silicon wafers
  • 文献类型:   Article
  • 作  者:   IACOPI F, MISHRA N, CUNNING BV, GODING D, DIMITRIJEV S, BROCK R, DAUSKARDT RH, WOOD B, BOECKL J
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS RESEARCH
  • ISSN:   0884-2914 EI 2044-5326
  • 通讯作者地址:   Griffith Univ
  • 被引频次:   22
  • DOI:   10.1557/jmr.2015.3
  • 出版年:   2015

▎ 摘  要

We introduce a novel approach to the synthesis of high-quality and highly uniform few-layer graphene on silicon wafers, based on solid source growth from epitaxial 3C-SiC films. Using a Ni/Cu catalytic alloy, we obtain a transfer-free bilayer graphene directly on Si(100) wafers, at temperatures potentially compatible with conventional semiconductor processing. The graphene covers uniformly a 2 '' silicon wafer, with a Raman I-D/I-G band ratio as low as 0.5, indicative of a low defectivity material. The sheet resistance of the graphene is as low as 25 Omega/square, and its adhesion energy to the underlying substrate is substantially higher than transferred graphene. This work opens the avenue for the true wafer-level fabrication of microdevices comprising graphene functional layers. Specifically, we suggest that exceptional conduction qualifies this graphene as a metal replacement for MEMS and advanced on-chip interconnects with ultimate scalability.