• 文献标题:   A new route to graphene starting from heavily ozonized fullerenes: Part 1-thermal reduction under inert atmosphere
  • 文献类型:   Article
  • 作  者:   CATALDO F, PUTZ MV, URSINI O, ANGELINI G, GARCIAHERNANDEZ DA, MANCHADO A
  • 作者关键词:   graphene, fullerene ozopolymer, graphite oxide, tgaftir, thermal reduction
  • 出版物名称:   FULLERENES NANOTUBES CARBON NANOSTRUCTURES
  • ISSN:   1536-383X EI 1536-4046
  • 通讯作者地址:   Actinium Chem Res Srl
  • 被引频次:   10
  • DOI:   10.1080/1536383X.2015.1101535
  • 出版年:   2016

▎ 摘  要

It is shown that heavily ozonized C-60 or C-70 fullerenes ( known also as " fullerene ozopolymers") are suitable substrates for the preparation of graphene or nanographene in place of graphite oxide ( GO) by thermal reduction in inert atmosphere. TGA-FTIR study shows that the release profile of CO2 and CO from fullerene ozopolymers in the temperature range between 25 degrees C and 900 degrees C is comparable to that shown by GO. Furthermore, the FT-IR spectral evolution of fullerene ozopolymers from room temperature to 630 degrees C under inert atmosphere is once again strikingly comparable to that observed on GO under the same conditions.