• 文献标题:   GRAPHENE OXIDE FUNCTIONALIZED BY ETHYLENE DIAMINE TETRAACETIC ACID (EDTA) BY A HYDROTHERMAL PROCESS AS AN ADSORBENT FOR NICKEL IONS
  • 文献类型:   Article
  • 作  者:   TOHAMY HAS, KAMEL S, ELSAKHAWY M
  • 作者关键词:   graphene oxide, edta, heavy metal ion, ni ii ion, adsorption, water pollution
  • 出版物名称:   CELLULOSE CHEMISTRY TECHNOLOGY
  • ISSN:   0576-9787
  • 通讯作者地址:  
  • 被引频次:   7
  • DOI:  
  • 出版年:   2021

▎ 摘  要

Graphene oxide (GO) from sugar cane bagasse (SCB/F) was treated with EDTA to produce modified GO (EGO) by a hydrothermal preparation reaction. Raman spectra showed an intensity ratio of I-D/I-G for SCB/F and EGO8:1 (EDTA:GO 8:1) of 0.598 and 0.391, respectively. FTIR spectra confirmed the introduction of nitrogen-containing groups into the SCB/F backbone. SEM analysis demonstrated the porosity character for the sample. The TGA/DTA results implied the EGO8:1 sample was less thermally stable than SCB/F. The Ni2+ adsorption study revealed a steadily increasing adsorption of Ni2+ until 45 min, with no noticeable increase in adsorption after that. The results of kinetic modeling, adsorption isotherms, and thermodynamic parameters showed that the pseudo- second-order models gave a better fit to the adsorption data of the SCB/F and EGO samples. Also, the adsorption data fitted the Langmuir model best, and the negative values of Delta G indicated that the sorption process was spontaneous.