• 文献标题:   Fabrication and Properties of Graphene Oxide-reinforced Carrageenan Film
  • 文献类型:   Article
  • 作  者:   ZUO PP, ZHANG YL, FENG HF, XIA W, ZHANG WQ, WANG MZ
  • 作者关键词:   kappacarrageenan, graphene oxide, composite film, property
  • 出版物名称:   CHEMICAL JOURNAL OF CHINESE UNIVERSITIESCHINESE
  • ISSN:   0251-0790
  • 通讯作者地址:   E China Univ Sci Technol
  • 被引频次:   2
  • DOI:   10.7503/cjcu20120685
  • 出版年:   2013

▎ 摘  要

Graphene oxide (GO) was synthesized using a modified Hummer's method. GO and kappa-Carrageenan(kappa-Car) film (GO/kappa-Car film) was prepared via tape casting and characterized by IR, SEM, and TGA. We optimized the formula and preparation conditions of GO/kappa-Car film by single-factor experiment to obtain the proper appearance, solubility, water vapor permeation and mechanical properties. The stable film was fabricated as follows 15. 0 g 3% kappa-Car solution, 0. 040 g GO powder and 5. 0 g 8% PVA solution were mixed by intensely stirring for 5 h at 75 degrees C. The mixture was then cast evenly, kept at 30 degrees C for 6. 5 h and peeled off as a free-standing film. Compared with the kappa-Car film, the mechanical properties of the GO/kappa-Car film were significantly improved. With incorporation of 5. 0 % GO, the peak load, tensile strength and tensile modulus of the GO/kappa-Car film are improved by 1. 5-fold, 1. 5-fold and 1. 6-fold, respectively. Meanwhile, GO/kappa-Car film has good water vapor permeability as well as hydroxyl radical scavenging activity.