• 文献标题:   An Electrochemical Hydroquinone Sensor with Nitrogen-Doped Graphene Modified Electrode
  • 文献类型:   Article
  • 作  者:   NIU XL, YAN LJ, LI XB, WEN ZR, YU JH, HU AH, DONG LF, SHI ZF, SUN W
  • 作者关键词:   nitrogendoped graphene, carbon ionic liquid electrode, hydroquinone, electrochemistry, electrochemical sensor
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Hainan Normal Univ
  • 被引频次:   8
  • DOI:   10.20964/2016.08.65
  • 出版年:   2016

▎ 摘  要

In this paper a solvethermal synthesized nitrogen-doped graphene (NG) was used as modifier on carbon ionic liquid electrode (CILE) to get a novel modified electrode, which was denoted as NG/CILE. An electrochemical hydroquinone (HQ) sensor was constructed with NG/CILE as working electrode. Electrochemical behaviors of HQ on NG/CILE were investigated by cyclic voltammetry with a pair of redox peaks observed. Compared with that of CILE, electrochemical responses of HQ were enhanced greatly with the peak-to-peak separation reduced. The result indicated good electrocatalytic ability of NG/CILE to the redox reaction of HQ. Under the optimal conditions a wider linear response between the peak current and HQ concentration was established in the concentration range from 0.2 to 800.0 mu mol L-1 accompanied by a detection limit of 0.625 mol L-1 (3 sigma). Furthermore, the as-proposed HQ sensor exhibited high sensitivity and good selectivity toward HQ detection, which was successful applied to the synthetic water samples analysis.