• 文献标题:   Numerous single-layer graphene sheets prepared from natural graphite by non-chemical liquid-phase exfoliation
  • 文献类型:   Article
  • 作  者:   HSU PC, LIN TA, TSAI IS
  • 作者关键词:  
  • 出版物名称:   MICRO NANO LETTERS
  • ISSN:   1750-0443
  • 通讯作者地址:   Feng Chia Univ
  • 被引频次:   2
  • DOI:   10.1049/mnl.2014.0415
  • 出版年:   2014

▎ 摘  要

A simple method was used to produce a high concentration of single-layer graphene sheets in a single organic solvent system, without using any surfactants. In this experiment, the concentration of single-layer graphene sheets dispersed in solution increased as the sonication time increased, but damage occurred after performing sonication for 120 min. The concentration of single-layer graphene sheets was 0.915 mg/ml after sonication for 60 min. According to a transmission electron microscope image, the length of the single-layer graphene sheets was similar to 2-3 mu m, and the width was 0.5-1 mu m. The perfect single-layer graphene sheets and the defective single-layer graphene sheets were distinguished using selected-area electron diffraction. X-ray diffraction determined that the two-theta angle of the numerous single-layer graphene sheets on a (002) plane was 25.57 degrees, but the 'one layer' graphene sheets produced no peak along the (002) plane. According to the Raman spectra, the ratio of I-D/I-G was 0.3, which indicated that the graphene sheets contained few defects.