• 文献标题:   Structural regulatory mechanism of phosphotungstate acid decorated graphene oxide quantum dots-chitosan aerogel and its application in ciprofloxacin degradation
  • 文献类型:   Article
  • 作  者:   LI PP, WANG Z, YANG SC, LYU G, GU YW, CHEN JC, YANG GH
  • 作者关键词:   chitosan, graphene oxide quantum dot, phosphotungstate acid, pre adsorption photocatalysis proces, ciprofloxacin degradation
  • 出版物名称:   INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
  • ISSN:   0141-8130 EI 1879-0003
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.ijbiomac.2023.125137 EA JUN 2023
  • 出版年:   2023

▎ 摘  要

Chitosan modified AGQD (amine modified graphene oxide quantum dots) and then combined with H3PW12O40 to obtain CSx@AGQD-HPW12 via facile process and applied for CIP removal through pre-adsorption and photocatalytic processes. The application of chitosan could regulate the morphology and photoelectric properties effectively. CS0.5@AGQD-HPW12 was found to have the optimal CIP removal performance among all the products, the corresponding adsorption removal efficiency and pre-adsorption photocatalysis process were 72.1 % and 98.8 %, respectively. Results of toxicity assessment confirmed photocatalytic degradation process could mitigate the ecotoxicity of CIP effectively. The optimal TOC (total organic carbon) removal efficiency was about 52.1 %. Possible pathways for CIP degradation and reaction mechanism were proposed based on the results of intermediates analysis and trapping experiments. This demonstrated a novel approach to chitosan application and an eco-friendly way to remove CIP by adsorption-photocatalysis process.