▎ 摘　　要

Ni-Co layered double hydroxide (Ni-Co LDH) nanosheet is a promising electrode material for high-performance supercapacitors, but it has low specific capacity and poor rate performance due to its low conductivity. In this paper, a high specific surface area zeolite-based metal organic framework (MOF) dodecahedral cobalt-based nanomaterial (ZIF-67) was used as a cobalt source and a sacrificial template. The ZIF-67 template was etched by the hydrolysis of Ni(2+)at room temperature; LDH materials are coprecipitated in solution. The material has a hierarchical structure of interdigitated nanosheet arrays, and the ordered nanosheet array facilitates effective contact of the active material with the electrolyte and rapid diffusion of ions. The conductive graphene is coated on the foamed nickel (rGO/NF) to form an excellent conductive structural support, thereby accelerating the transmission of electrons on the substrate. At a current density of 1 A g(-1), the specific capacitance of Ni-Co LDH/rGO/NF is as high as 2505 F g(-1). When the current density is increased to 20 A g(-1), the capacity retention can reach 81%. An asymmetric capacitor was assembled by using Ni-Co LDH/rGO/NF as the positive electrode and biomass-derived nitrogen-doped porous carbon (QPC) as the negative electrode with an operating voltage range of 0-1.5 V. The Ni-Co LDH/rGO/NF//QPC asymmetric supercapacitor has an energy density of 76 Wh kg(-1)at a power density of 747.5 W kg(-1). When the power density reaches 7486.6 W kg(-1), the energy density is still 35 Wh kg(-1).