• 文献标题:   Amino Acid Cross-Linked Graphene Oxide Membranes for Metal Ions Permeation, Insertion and Antibacterial Properties
  • 文献类型:   Article
  • 作  者:   QIAN LJ, WANG HJ, YANG JY, CHEN XL, CHANG X, NAN Y, HE ZY, HU PZ, WU WS, LIU TH
  • 作者关键词:   graphene oxide membrane, crosslinking, amino acid, metal ion, rejection
  • 出版物名称:   MEMBRANES
  • ISSN:  
  • 通讯作者地址:   Lanzhou Univ
  • 被引频次:   0
  • DOI:   10.3390/membranes10100296
  • 出版年:   2020

▎ 摘  要

Graphene oxide (GO) and its composite membranes have exhibited great potential for application in water purification and desalination. This article reports that a novel graphene oxide membrane (GOM) of similar to 5 mu m thickness was fabricated onto a nylon membrane by vacuum filtration and cross-linked by amino acids (L-alanine, L-phenylalanine, and serine). The GOM cross-linked by amino acids (GOM-A) exhibits excellent stability, high water flux, and high rejection to metal ions. The rejection coefficients to alkali and alkaline earth metal ions through GOM-A were over 94% and 96%, respectively. The rejection coefficients decreased with an increasing H+ concentration. Metal ions (K+, Ca2+, and Fe3+) can be inserted into GOM-A layers, which enlarges the interlayer spacing of GOM-A and neutralizes the electronegativity of the membrane, resulting in the decease in the rejection coefficients to metal ions. Meanwhile, GOM-A showed quite high antibacterial efficiency against E. coli. With the excellent performance as described above, GOM-A could be used to purify and desalt water.