• 文献标题:   Electrochemical study of reduced graphene oxide@Zn2Ti3O8 nanocomposites as a superior anode for Li-ion battery
  • 文献类型:   Article
  • 作  者:   CHENG WJ, WANG X, HUANG JF, WANG Y, YIN LX, LI JY, KONG XA, FENG Q
  • 作者关键词:   lithiumion battery, anode, 2d nanocomposite, zn2ti3o8, pseudocapacitance
  • 出版物名称:   CHEMICAL ENGINEERING SCIENCE
  • ISSN:   0009-2509 EI 1873-4405
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.ces.2022.117872 EA JUL 2022
  • 出版年:   2022

▎ 摘  要

In this paper, a high-performance Li-ion battery anode, 2D reduced graphene oxide@Zn2Ti3O8 nanocomposite was successfully synthesized. In the mixing process, the porous Zn2Ti3O8 nanoplate and the reduced graphene oxide flakes were closely bonded by the electrostatic force, and then the heterojunction formed between them after 600 ? heat treatment in the N-2 atmosphere. Due to the introduction of graphene, the electrochemical impedance of the composite is much reduced, and this two-dimensional heterostructure induced a large number of pseudocapacitance behaviors, which greatly increased the rate performance, cycling stability, and reversible capacity. In the long cycle performance tests at high current densities, the reduced graphene oxide@Zn2Ti3O8 composite can maintain stable capacities of 600 mAh g(-1 )at 1000 mA g(-1)and 265 mAh g(-1) at 5000 mA g(-1), exceeding all previous reports of Zn2Ti3O8 electrode. The excellent performance of the nanocomposite under high current density makes it a potential anode material for lithium-ion batteries. (C) 2022 Published by Elsevier Ltd.