• 文献标题:   Voltammetric determination of Sudan I in food samples based on platinum nanoparticles decorated on graphene-beta-cyclodextrin modified electrode
  • 文献类型:   Article
  • 作  者:   PALANISAMY S, KOKULNATHAN T, CHEN SM, VELUSAMY V, RAMARAJ SK
  • 作者关键词:   sudan i, graphene, betacyclodextrin, platinum nanoparticle, modified electrode, food analysi
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Natl Taipei Univ Technol
  • 被引频次:   18
  • DOI:   10.1016/j.jelechem.2017.03.041
  • 出版年:   2017

▎ 摘  要

In the present work, we report a sensitive and low level electrochemical detection of Sudan I in food samples using platinum nanoparticles (PtNPs) decorated graphene-beta-cyclodextrin (graphene/beta-CD) modified electrode for the first time. Cyclic voltammetry was used to evaluate the electrochemical behavior of different modified electrodes towards Sudan I. Cyclic voltammetry results reveal that graphene/beta-CD/PtNPs composite modified electrode has high electrocatalytic activity towards Sudan I than other modified electrodes. Under optimum conditions, the graphene/beta-CD/PtNPs composite modified electrode detects the Sudan I in the linear response ranging from 0.005 to 68.68 mu M with a lower limit of detection of 1.6 nM. As a proof of concept, the graphene/beta-CD/PtNPs composite modified was used for the determination of Sudan I in chili powder, chili sauce, tomato sauce and ketchup and found satisfactory recovery of Sudan I. Therefore, the fabricated sensor can be used for the detection of Sudan I in adulterated food samples. (C) 2017 Elsevier B.V. All rights reserved.