• 文献标题:   Advanced Catalytic and Electrocatalytic Performances of Polydopamine-Functionalized Reduced Graphene Oxide-Palladium Nanocomposites
  • 文献类型:   Article
  • 作  者:   FU L, LAI GS, ZHU DM, JIA BH, MALHERBE F, YU AM
  • 作者关键词:   electrochemistry, graphene, oxidation, palladium, polymer
  • 出版物名称:   CHEMCATCHEM
  • ISSN:   1867-3880 EI 1867-3899
  • 通讯作者地址:   Swinburne Univ Technol
  • 被引频次:   11
  • DOI:   10.1002/cctc.201600532
  • 出版年:   2016

▎ 摘  要

A polydopamine-functionalized reduced graphene oxide (PDARGO)/Pd nanocomposite was synthesized by a simple wet chemical approach at room temperature. Graphene oxide (GO) was first modified with PDA by the self-polymerization of dopamine (DA) followed by the deposition of Pd nanoparticles. UV/Vis and FTIR spectroscopies confirmed the reduction of GO to RGO during the self-polymerization of DA. SEM images revealed that Pd nanoclusters were formed on both sides of the PDA-RGO sheets. The as-prepared PDA-RGO/Pd nanocomposites exhibited excellent catalytic activity in the chemical degradation of methylene blue with a reaction rate constant of 0.6028 min(-1), which was 2.5-fold faster than that of the PDA/Pd catalyst without RGO. Moreover, the PDA-RGO/Pd nanocomposite also showed an outstanding electrocatalytic activity towards the electro-oxidation of paracetamol. The current response had a linear relationship to the concentration of paracetamol in the range of 0.28-100 mu m with a low detection limit of 0.087 mu m (S/N=3). In addition, the sensor also exhibited good selectivity for the detection of paracetamol.