• 文献标题:   High-Speed Blow Spinning of Neat Graphene Fibrous Materials
  • 文献类型:   Article
  • 作  者:   LIU SP, WANG YZ, MING X, XU Z, LIU YJ, GAO C
  • 作者关键词:   high speed, blow spinning neat graphene fiber, graphene fabric, gas diffusion layer
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:  
  • 被引频次:   16
  • DOI:   10.1021/acs.nanolett.1c01076 EA JUN 2021
  • 出版年:   2021

▎ 摘  要

Achieving high spinning speed is critical to the production efficiency and viable application of fiber species. Graphene fiber (GF) has recently emerged as a carbonaceous fiber with excellent functionality. However, the extremely low wet spinning speed of GF has limited its applications. We realized high-speed blow spinning of neat GF and fabric by modulating the rheological properties of the graphene oxide (GO) dispersion. We achieved a speed of 556 m min(-1), 2 orders of magnitude faster than that for wet spinning. We chose ultrahigh molecular weight polymers as transient additives to circumvent the intrinsic barrier effect of GO and achieve high spinning dope stretchability at low polymer percentages-down to 25 wt %. Minimizing the polymer additive content ensures the high electrical/thermal conductivity of the blow-spun fiber and fabric. This work provides insight into the unique flow properties of 2D sheets and will promote the efficient production of graphene-based fibrous materials.