• 文献标题:   Adsorption behavior of thorium on N,N,N ',N '-tetraoctyldiglycolamide (TODGA) impregnated graphene aerogel
  • 文献类型:   Article
  • 作  者:   CHEN MM, LI Z, GENG YY, ZHAO HG, HE SH, LI QN, ZHANG L
  • 作者关键词:   graphene aerogel, todga, solvent impregnated adsorbent, thorium
  • 出版物名称:   TALANTA
  • ISSN:   0039-9140 EI 1873-3573
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   12
  • DOI:   10.1016/j.talanta.2018.01.020
  • 出版年:   2018

▎ 摘  要

As a kind of three-dimensional graphene architecture material with superhydrophobic, low density, high specific surface area and porosity, graphene aerogel (GA) can be used to immobilize extractant to constitute the solvent impregnated adsorbent. In this paper, the N,N,N',N'-tetraoctyldiglycolamide impregnated graphene aerogel (GA-TODGA) was prepared to remove the thorium from aqueous solution. It is found that the adsorption of thorium on GA-TODGA is strongly dependent on the concentration of TODGA in GA and HNO3 in aqueous solution. Compared with other solvent impregnated adsorbents, the adsorption capacity of GA-TODGA is much higher due to the high immobilization capacity of GA for TODGA. Furthermore, the GA-TODGA also possesses excellent stability and reusability, ensuring the application potential of using GA-TODGA in large scale.