• 文献标题:   Nitrogen and sulfur co-doped graphene composite electrode with high electrocatalytic activity for vanadium redox flow battery application
  • 文献类型:   Article
  • 作  者:   LI Q, BAI AY, XUE ZC, ZHENG Y, SUN H
  • 作者关键词:   sulfur, nitrogen, vanadium redox flow battery, graphene, thiourea
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Shenyang Jianzhu Univ
  • 被引频次:   0
  • DOI:   10.1016/j.electacta.2020.137223
  • 出版年:   2020

▎ 摘  要

Nitrogen and sulfur co-doped graphene has been decorated on graphite felt electrode via a hydrothermal treatment using thiourea as sulfur and nitrogen sources for vanadium redox flow battery application. Our results demonstrate that the modification of sulfur and nitrogen co-doped graphene on graphite felt provides an effective way to improve surface area and introduce functional groups for vanadium redox reaction, resulting in a significant improvement in energy efficiency (85.37% at a current density of 80 mA/cm(2)), power density (0.4925 W/cm(2)), discharge capacity and capacity retention. These results reveal that the modification of nitrogen and sulfur co-doped graphene on graphite felts is a promising method for the enhancement of vanadium redox flow battery performance. (C) 2020 Elsevier Ltd. All rights reserved.