• 文献标题:   Assembling and nanocutting graphene/CNT sponge for improved lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   SANG Y, ZHOU Y, XIE H, WANG CD, SONG L
  • 作者关键词:   hybridized graphene/cntsponge, nanocutting, porous structure, lithium ion battery, supercapacitor
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Univ Sci Technol China
  • 被引频次:   2
  • DOI:   10.1007/s11581-017-2031-z
  • 出版年:   2017

▎ 摘  要

Graphene-based materials have exhibited high potential for applications in the field of energy generation and storage because of its high surface area and porosity. Herein, we present a facile strategy to assemble graphene/carbon nanotubes into well-dispersed three-dimensional sponge and subsequently cut nano-scale pores via nickel nanoparticles for enhancing anode's performance in lithium-ion batteries. Our characterizations reveal that the hybrid aerogels exhibit a lot of nanoscale channels and pores due to the Ni-nanocutting process, resulting in an improved specific surface area 254 m(2)/g in contrast with 187 m(2)/g for the pristine materials. The hybrid aerogels are subsequently used as anode for lithium-ion battery and exhibit a greatly improved performance after nanocutting treatment. Meanwhile, the specific capacity of supercapacitor with the Ni-cutting aerogel electrode can achieve as high as 475 F/g, which is almost 68 times than that of the pure material (7 F/g). This route may open a facile engineering way to produce porous and high performance electrode for specific electrochemical applications.