• 文献标题:   Synthesis and optical properties of nitrogen and sulfur co-doped graphene quantum dots
  • 文献类型:   Article
  • 作  者:   ZHANG BX, GAO H, LI XL
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Lanzhou Univ
  • 被引频次:   81
  • DOI:   10.1039/c4nj00965g
  • 出版年:   2014

▎ 摘  要

Strong blue luminescence and water-soluble nitrogen (N) and sulfur (S) co-doped graphene quantum dots (NS-GQDs) were fabricated via a one-step hydrothermal method using oxidized graphene. Ammonia and powdered S were selected as the source of N and S. respectively. The results indicated that both N and S atoms were successfully incorporated into the sp(2)-hybridized carbon framework of graphene. Under the excitation of 365 nm, the maximum emission intensity could be obtained with a 1:1.2 atomic ratio of N/S. The as-prepared NS-GQDs exhibited brighter luminescence compared with N-doped graphene quantum dots (N-GQDs). S-doping plays an important role in enhancing the emission intensity of NS-GQDs. In addition, the luminescence was exceptionally resistant to high salt concentration. Because of these virtues, there are extensive potential applications for NS-GQDs in bio-imaging, solar cells, and ion detection.