• 文献标题:   Alkali-induced hydrogenation of epitaxial graphene by water splitting at 100 K
  • 文献类型:   Article
  • 作  者:   POLITANO A, CHIARELLO G
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF CHEMICAL PHYSICS
  • ISSN:   0021-9606 EI 1089-7690
  • 通讯作者地址:   Univ Calabria
  • 被引频次:   10
  • DOI:   10.1063/1.4788619
  • 出版年:   2013

▎ 摘  要

The coadsorption of potassium with water at 100 K on graphene/Pt(111) has been studied by high-resolution electron energy loss spectroscopy. The adsorption of alkali metals induces water splitting and the formation of C-H and C-OH groups. Such finding is of great interest for tailoring graphene-Pt electro-catalysts. Furthermore, the alkali-promoted dissociation of water molecules offers the possibility to attain a partial hydrogenation of the graphene sheet even at low temperature. (C) 2013 American Institute of Physics. [http://dx.doi.org/10.1063/1.4788619]