• 文献标题:   Construction of hierarchical porous graphene-carbon nanotubes hybrid with high surface area for high performance supercapacitor applications
  • 文献类型:   Article
  • 作  者:   WANG DW, FANG GL, ZHENG Q, GENG GH, MA JF
  • 作者关键词:   graphene, energy storage, carbon nanotube, supercapacitor, porosity
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Beifang Univ Nationalities
  • 被引频次:   10
  • DOI:   10.1007/s10008-016-3403-4
  • 出版年:   2017

▎ 摘  要

Unlike activated carbon, graphene sheets are lack of ion pathways on their basal planes and prone to agglomerate or restack unfortunately for their strong pi - pi interactions between neighboring sheets. All of which will pose significant obstacles for its application in high performance supercapacitors. Herein, we report a simple and fast strategy for the scalable synthesis of hierarchical honeycomb-like porous graphene-carbon nanotubes hybrid (PGCTs) through a simple laser induced self-propagating reaction process and subsequent activation with low amount of KOH without any template. Benefiting from properly integration of large surface area, hierarchical pore structures, in-plane nanopores and CNTs nanospacers, the as-obtained PGCTs based symmetrical supercapacitor exhibits outstanding electrochemical performance with super capacitance, excellent rate capability, and desirable cyclability.