• 文献标题:   High-performance hybrid supercapacitor with electrochemically exfoliated graphene oxide incorporated NiCo2O4 in aqueous and non-aqueous electrolytes
  • 文献类型:   Article
  • 作  者:   PAPPU S, ANANDAN S, RAO TN, MARTHA SK, BULUSU SV
  • 作者关键词:   electrochemical exfoliation, nico 2 o 4 ego composite, organic electrolyte, energy density, power density
  • 出版物名称:   JOURNAL OF ENERGY STORAGE
  • ISSN:   2352-152X EI 2352-1538
  • 通讯作者地址:  
  • 被引频次:   8
  • DOI:   10.1016/j.est.2022.104598 EA APR 2022
  • 出版年:   2022

▎ 摘  要

Hydrothermal approach is employed to synthesize electrochemically exfoliated graphene oxide (EGO) integrated NiCo2O4 micro-flowers with nano petals. Specific capacity of 59 mAh g-1 (530 F g-1) is achieved by the optimized weight percentage of EGO in NiCo2O4 with long cyclic stability over 10,000 cycles. Detailed analysis on charge-storage properties of NiCo2O4-EGO composite reveals individual capacitive and diffusive contributions at various scan rates. An asymmetric supercapacitor device is fabricated with EGO incorporated NiCo2O4 composite material and commercial YP-50F carbon as positive and negative electrodes in 1 M TEABF4 acetonitrile organic electrolyte for the first time. The device delivers promising electrochemical performance with energy and power densities of 37.8 Wh kg-1 and 1350 W kg-1. Present work suggests an eco-friendly synthesis of EGO and provides a cost-effective facile approach for improving the overall electronic conductivity and cyclic stability of NiCo2O4 and other similar metal oxide materials for high-performance supercapacitors.