• 文献标题:   Intrinsic peroxidase-like catalytic activity of nitrogen-doped graphene quantum dots and their application in the colorimetric detection of H2O2 and glucose
  • 文献类型:   Article
  • 作  者:   LIN LP, SONG XH, CHEN YY, RONG MC, ZHAO TT, WANG YR, JIANG YQ, CHEN X
  • 作者关键词:   nitrogendoped graphene quantum dot, intrinsic peroxidaselike catalytic activity, colorimetric detection, h2o2 glucose sensing
  • 出版物名称:   ANALYTICA CHIMICA ACTA
  • ISSN:   0003-2670 EI 1873-4324
  • 通讯作者地址:   Xiamen Univ
  • 被引频次:   115
  • DOI:   10.1016/j.aca.2015.02.024
  • 出版年:   2015

▎ 摘  要

In this paper, the highly intrinsic peroxidase-like catalytic activity of nitrogen-doped graphene quantum dots (N-GQDs) is revealed. This activity was greatly dependent on pH, temperature and H2O2 concentration. The experimental results showed that the stable N-GQDs could be used for the detection of H2O2 and glucose over a wide range of pH and temperature, offering a simple, highly selective and sensitive approach for their colorimetric sensing. The linearity between the analyte concentration and absorption ranged from 20 to 1170 mu M for H2O2 and 25 to 375 mu M for glucose with a detection limit of 5.3 mu M for H2O2 and 16 mu M for glucose. This assay was also successfully applied to the detection of glucose concentrations in diluted serum and fruit juice samples. (C) 2015 Elsevier B.V. All rights reserved.