• 文献标题:   Structure and properties of graphene oxide/cellulose hybrid fibers via divalent metal ions treatment
  • 文献类型:   Article
  • 作  者:   RYU J, LIM JS, AHN S, JO SM, KO FK, LEE JH, HWANG JY
  • 作者关键词:   nano hybrid material, cellulose fiber, graphene oxide, metal ion, mechanical propertie
  • 出版物名称:   CELLULOSE
  • ISSN:   0969-0239 EI 1572-882X
  • 通讯作者地址:   Korea Inst Sci Technol
  • 被引频次:   1
  • DOI:   10.1007/s10570-017-1535-z
  • 出版年:   2018

▎ 摘  要

Cellulose hybrid fibers (CeHFs), hybridized via graphene oxide (GO) and metal ions (Ca2+), are synthesized by dry-jet wet spinning. The synthesized GO-Ca2+-CeHFs exhibit the tensile strength and the breaking elongation of 551 +/- 37.5 MPa and 5.9 +/- 0.4%, respectively, while the GO/cellulose composite fibers (GO-CeFs) show the tensile strength of 403 +/- 76.0 MPa and the elongation of 4.5 +/- 0.5%; thus, the GO-Ca2+-CeHFs demonstrate improved mechanical properties over GO-CeFs by 37 and 31% in terms of tensile strength and elongation, respectively. These results are attributed to the metal ions that form a good interfacial interaction between the functional groups of cellulose and GO. In addition, the tensile strength of GO-Ba2+-CeHFs is as high as 580 +/- 25 MPa, which is induced by the difference in the ionic radius. Therefore, the high mechanical properties of the synthesized cellulose-based fibers have the potential to be used as sustainable alternative to the synthetic fibers used in the industrial applications.