• 文献标题:   Improved removal of lead(II) from water using a polymer-based graphene oxide nanocomposite
  • 文献类型:   Article
  • 作  者:   MUSICO YLF, SANTOS CM, DALIDA MLP, RODRIGUES DF
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Univ Houston
  • 被引频次:   88
  • DOI:   10.1039/c3ta01616a
  • 出版年:   2013

▎ 摘  要

Poly(N-vinylcarbazole) (PVK) was blended with graphene oxide (GO) to form a PVK-GO polymer nanocomposite capable of adsorbing heavy metal from aqueous solutions. The homogenous distribution of GO in the PVK-GO nanocomposite was determined by X-ray photoelectron microscopy (XPS) and attenuated total reflectance -infrared spectroscopy (ATR-IR). The results show that the adsorption capacity of Pb2+ by the nanocomposite increased with increasing amount of GO. This phenomenon was attributed to the increasing concentration of oxygen-containing functional groups available in the nanocomposite. Furthermore, the adsorption of Pb2+ onto PVK-GO nanocomposite was influenced by pH changes. Higher pHs had a better adsorption capacity than lower pHs, due to changes in the nanocomposite surface properties. The highest adsorption capacity of the PVK-GO nanocomposite for Pb2+ was 887.98 mg g(-1) and fits well the Langmuir model. This adsorption capacity was achieved using a 10 : 90 wt% ratio of PVK : GO at pH 7 +/- 0.5 with a 90 min contact time. The high removal efficiency of this nanocomposite suggests that PVK-GO is effective and can be applied to remove heavy metals from water.